Silver stain removal (& other thoughts. Was: Thanks)
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From: | "J. A. Kiernan" <jkiernan@julian.uwo.ca> |
To: | Inka Tertinegg <inka@playfair.utoronto.ca> |
Reply-To: | |
Date: | Sat, 27 Mar 1999 00:49:08 -0500 (EST) |
Content-Type: | TEXT/PLAIN; charset=US-ASCII |
On Fri, 26 Mar 1999, Inka Tertinegg wrote:
> Does anyone know how to get silver stain out of
> a white benchtop?
Inka: It depends how tough the bench top is.
1. Nitric acid will remove silver (but not gold).
Dilute the conc. acid about 50/50 with water.
OK on epoxy paint. I don't know about formica,
but would guess probably safe at this dilution.
2. (From back in the old days) A paste of mercuric
chloride and water rubbed into the black silver
stain. More gentle on the skin than nitric acid,
I've been told. Never really an acceptable method.
3. Farmer's reducer, as used in photography; but for
cleaning purposes it needs to be more concentrated.
Crunch up about one cubic centimetre each of
potassium ferricyanide and sodium thiosulphate in
15-20 ml of water. Apply generously to the blackened
bits of bench. It will remove the silver but not
quickly. Allow 30-60 minutes and don't let it dry
out. The slowness is a penalty for (a) spilling
your expensive silver solution, and (b) using fairly
harmless chemicals.
Be sure to use ferrIcyanide and NOT ferrOcyanide,
which will not work. Despite the -cyanide in their
names, these are not considered dangerous poisons.
(Cyanides, well known for their speed, are much more
potent and also easily available to murderers in
detective stories. When I was a lad, one of the
other students in the lab needed to order some
KCN for histochemical purposes. He needed about
50 mg but the stuff was cheap and the smallest
bottle held 500 g. We looked it up in Polson's
Toxicology and found that this would be enough to
kill 1500 people, if they could all be
persuaded to swallow their 333 mg helpings. The
smell must surely make cyanide a rather poor
weapon for the enterprising poisoner: "bitter
almonds" to the novelist, but "sickly sweet" to
anyone working with amounts well below 10% of what's
supposed to be lethal.)
4. None of these methods will remove dark stains due to
metallic gold, from spilt "gold chloride." Cyanide
and oxygen would, and so would aqua regia, but these
are not for sploshing on the bench's top. To hide
carelessness with gold, you'll need a pot of paint.
John A. Kiernan,
Department of Anatomy & Cell Biology,
The University of Western Ontario,
LONDON, Canada N6A 5C1
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